کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5201155 1502888 2016 31 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Compatibility, mechanical properties and stability of blends of polylactide and polyurethane based on poly(ethylene glycol)-b-polylactide copolymers by chain extension with diisocyanate
ترجمه فارسی عنوان
سازگاری، خواص مکانیکی و پایداری مخلوط های پلی و اتیلن و پلی اورتان بر اساس پلی اتیلن گلیکول - ب - پلی اتیلن کپسول های پلی اتیلن با افزودن زنجیره ای با دی ایزوسیانات
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
A series of novel biodegradable polyurethanes (PELU) based on poly(ethylene glycol)-b-polylactide copolymers were prepared by chain extension with isophorone diisocyanate (IPDI). The PELUs were used to toughen polylactide (PLA) by melt blending. The results of DSC and SEM uniformly indicated that the PELUs were partially compatible with PLA and the PLA segments in PELU could effectively improve the compatibility between PLA and PELU. PELU as a plasticizer could significantly improve the toughness of PLA materials and remain their high strength and modulus. When the PELU content was 10-20 wt%, the elongation at break of PLA/PELU-40/ADR (0.4 wt%) and PLA/PELU-50/ADR (0.4 wt%) reached up to 250%-350%. When the PELU content was 20 wt%, the tensile strength and modulus of PLA blends containing PELU-30, PELU-40 and PELU-50 maintained 35-38 MPa and 1300-1500 MPa, respectively. The moisture absorption of the PLA materials enhanced because of blending with PELU containing PEG segments, but the hydrolytic degradation property of PLA materials was little affected by this.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 125, March 2016, Pages 148-155
نویسندگان
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