کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5201705 1502904 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and properties of deeply oxidized waster rubber crumb through long time ozonization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Structure and properties of deeply oxidized waster rubber crumb through long time ozonization
چکیده انگلیسی

Deeply oxidization of waster rubber crumb (WRC) by ozone treatment was carried out at room temperature with long time exposure. Gel content measurement, TG/DTG (thermogravimetric) analysis, ATR-FTIR (attenuated total reflectance-Fourier transform infrared) spectroscopy, XPS (X-ray photoelectron spectroscopy) and mixing properties tests were used to investigate the structure and properties of deeply oxidized WRC. After ozone oxidation, the gel content of WRC decreased dramatically in the first 3 h and then decreased slowly with prolonging the oxidation time. TG/DTG results showed that few low molecule weight materials were produced although ozone did destroy some cross-linking networks by oxidizing decomposition. ATR-FTIR and XPS spectrum showed the increase of oxygen-containing groups in WRC, indicating that oxidation reaction between ozone and WRC happened. Deeply oxidized WRC could form a uniform plate under pressure and heat due to regaining part of the flowability.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 109, November 2014, Pages 1-6
نویسندگان
, , , , , , ,