کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5202740 | 1381908 | 2012 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal ageing behavior of styrene-butadiene random copolymer: A study on the ageing mechanism and relaxation properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The relaxation behavior of thermally degraded SBR was studied by DMA and DSC. Both of the two techniques evidenced an increasing and broadening Tg, suggesting the crosslinking reaction dominated thermal degradation. After checking the normalized spectra, it is found that all of the relaxation curves (irrespective of storage modulus, loss modulus or loss tangent) get widen over ageing. Two parameters, steepness (S) and wideness index (W) were defined in normalized storage modulus plot to make a quantitative discussion. The S reduced whereas the W rose up after degradation. The broader glass transition zone after ageing was attributed to the more heterogeneous relaxation environment and the wider size distribution of motion units participating in the transition.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 97, Issue 9, September 2012, Pages 1704-1715
Journal: Polymer Degradation and Stability - Volume 97, Issue 9, September 2012, Pages 1704-1715
نویسندگان
Kewei Xiang, Xiaoan Wang, Guangsu Huang, Jing Zheng, Jingyun Huang, Guangxian Li,