کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5202756 | 1381908 | 2012 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal and photocatalytic stability enhancement mechanism of poly(propylene carbonate) due to Cu(I) impurities
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Thermal and photocatalytic stability enhancement mechanism of poly(propylene carbonate) due to Cu(I) impurities Thermal and photocatalytic stability enhancement mechanism of poly(propylene carbonate) due to Cu(I) impurities](/preview/png/5202756.png)
چکیده انگلیسی
The thermal and photolytic decomposition of poly(propylene carbonate) (PPC) in the presence of a photoacid generator (PAG) was studied. The mechanism of previously observed shifts in the decomposition temperature of PPC was investigated. The decomposition temperature of PPC can be altered when PPC/PAG films contact copper metal. X-ray photoelectron spectroscopy (XPS) analysis showed that a small amount Cu(I) was incorporated into the PPC/PAG film causing the increased stability and the Cu(I) concentration was similar to that of the PAG. PPC/PAG temperature stability was studied for a number of iodonium and sulfonium-based PAGs. Every iodonium-based PAG showed a PPC decomposition temperature shift and no sulfonium-based PAG showed the thermal stability effect. It appears that Cu(I) interacts with iodonium in the cation of the PAG causing a change in the acid creation mechanism of the PAG.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 97, Issue 9, September 2012, Pages 1829-1837
Journal: Polymer Degradation and Stability - Volume 97, Issue 9, September 2012, Pages 1829-1837
نویسندگان
Erdal Uzunlar, Paul A. Kohl,