کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5202829 | 1381911 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ageing of different biodegradable polyesters blends mechanical and hygrothermal behavior
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The aim of this study is to better understand the performance of binary blends of biodegradable polyesters when exposed to hygrothermal ageing, in order to overcome some of their limitations such as water resistance. For this, blends have been prepared by extrusion using two P(L)LA (l-poly-(lactic acid)) of different molecular weights and PÉCL (poly-É-caprolactone). Mechanical properties over ageing are reported and compared to pure P(L)LA. Blending PÉCL to P(L)LA allowed to improve P(L)LA initial resilience. During ageing, crystallinity increase seemed to lower water uptake at short ageing times, while osmotic cracking was found to possibly occur in pure P(L)LA for long ageing times, thus increasing water uptake. Besides, P(L)LA/PÉCL blends water uptake remained constant over ageing. Finally, while P(L)LA resilience decrease could be related to chain scission, blend aptitude to elongation decrease was related to interphase decohesion, at long ageing times. Results showed P(L)LA molecular weight influence on both initial mechanical properties and water uptake.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 95, Issue 3, March 2010, Pages 262-269
Journal: Polymer Degradation and Stability - Volume 95, Issue 3, March 2010, Pages 262-269
نویسندگان
V. Berthé, L. Ferry, J.C. Bénézet, A. Bergeret,