کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5203457 1381932 2008 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermal degradation of poly(siloxane-urethane) copolymers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Thermal degradation of poly(siloxane-urethane) copolymers
چکیده انگلیسی

The aim of this study was to investigate the characteristics and mechanism of the degradation of poly(siloxane-urethane) (PSiU) copolymers by thermogravimetric analysis (TGA) and TGA coupled with Fourier-transform infra-red spectroscopy (TG-FTIR). The PSiU copolymers consisted of 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butanediol (1,4-BD), and OH-terminated polydimethylsiloxane (PDMS). In TGA they exhibited a two-stage degradation at 250-650 °C. The two stages of degradation have been found to comprise eight degradation steps and two interchange reactions, as revealed by TG-FTIR analysis. The main decomposition products have been identified as CO2, tetrahydrofuran, cyclosiloxane, and macrocyclic species. In addition, the effects of hard segment content (HSC) on the degradation and thermal stability of PSiU copolymers have been investigated by means of TG and DTG curves; notably, a stability region at 410-470 °C is caused by the cyclosiloxane, as verified by TG-FTIR.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 93, Issue 10, October 2008, Pages 1753-1761
نویسندگان
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