کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5204157 1381951 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
New developments in chemical modification of fire-safe rigid polyurethane foams
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
New developments in chemical modification of fire-safe rigid polyurethane foams
چکیده انگلیسی

This work reports the preparation of polyurethane-polyisocyanurate (PUR-PIR) foams containing different amounts of flame retardants (FRs) and a layered silicate nanoclay. An environmentally friendly blowing agent, a mixture of 1,1,1,3,3-pentafluorobutane and 1,1,1,2,3,3,3-heptafluoropropane (HFC 365/227), with small amount of water was used. The flame retarded PUR-PIR foams showed better fire resistance in comparison to classical PUR and unmodified PUR-PIR foams without deterioration of their functional properties. It was observed that when nanoclay was used in conjunction with flame retardants containing reactive bromine and phosphorus compounds, and zinc stannate, the flammability was significantly reduced. Expandable graphite was also used in some samples. As control samples for reference purposes three foam systems without any flame retardant were frothed: PUR, PUR-PIR and foams PUR-PIR modified by carbodiimide groups.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 93, Issue 11, November 2008, Pages 2071-2076
نویسندگان
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