کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5204175 1381952 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Evaluation of PFO formation from the biodegradation of a fluorotelomer-based urethane polymer product in aerobic soils
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Evaluation of PFO formation from the biodegradation of a fluorotelomer-based urethane polymer product in aerobic soils
چکیده انگلیسی

This study is the first to evaluate the rate of formation of perfluorooctanoate (PFO) from the aerobic biodegradation of a fluorotelomer-based urethane polymer and to use this information to assess the global environmental significance of this source. A fluorotelomer-based urethane polymer product test substance was studied in four aerobic soils over two years to determine the rate at which the fluorotelomer side-chains covalently bonded to the polymer backbone were cleaved and subsequently transformed to form the anions of perfluorocarboxylic acids including PFO. Over the two year duration of the experimental study, a polymer biodegradation half-life of 102 years (range: 28-241) was calculated for the urethane polymer based on regression analysis of the rate of PFO formation in four test soils. When this half-life was applied to the estimated total historic production, use and disposal of fluorotelomer-based urethane polymer, the annual potential global generation of PFO was estimated to be less than one tonne per year.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 95, Issue 1, January 2010, Pages 79-85
نویسندگان
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