کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5204388 | 1381959 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of stearate preheating on the thermal stability of plasticized PVC compounds
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Effect of preheating of stearates on the processing and post-processing thermal stability of poly(vinyl chloride) compounds, plasticized with di(2-ethylhexyl) phthalate (DEHP) and epoxidized soybean oil (ESO), using several ratios of calcium/zinc stearates and DEHP/ESO is reported. The compounds were prepared as follows: (1) dry-blending the compound components, (2) pelletizing the dry-blend and (3) extruding the pellets to obtain a ribbon geometry. Processing stability was determined by: (a) mechanical characterization and (b) visual color comparison of extruded samples. Post-processing thermal stability was followed by: (a) measurement of HCl release from heated pellets and (b) color changes in heated ribbon samples. From a practical point of view, the preheating has a negligible effect on the initial color of formulations; except for the case of formulations without both ESO and CaSt2. However, the effect of the preheating on the post-processing thermal stability is strongly determined by the composition formulation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 91, Issue 11, November 2006, Pages 2715-2722
Journal: Polymer Degradation and Stability - Volume 91, Issue 11, November 2006, Pages 2715-2722
نویسندگان
Luis J. González-Ortiz, Martin Arellano, M. Judith Sánchez-Peña, Eduardo Mendizábal, Carlos F. Jasso-Gastinel,