کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5204796 | 1381972 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
IR laser ablation of poly(vinyl chloride): Formation of monomer and deposition of nanofibres of chlorinated polyhydrocarbon
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
IR laser-induced ablation of poly(vinyl chloride) was examined under different irradiation conditions and its volatile and solid products were characterized by mass, infrared, UV and X-ray photoelectron spectroscopy, electron microscopy and thermogravimetry. It is demonstrated that the major component among the volatile products is monomeric vinyl chloride and that the process causes deposition of Cl-containing polymeric films. The proportion between the volatile and solid products as well as the nature of the deposited films at different laser fluences have been examined. We show that the deposited films incorporate less Cl atoms than poly(vinyl chloride) and that they initially contain conjugated CC bonds and incorporate nano-sized fibre and necklace features. The process represents the first example of thermal degradation of poly(vinyl chloride) into monomer and makes it possible to fabricate crosslinked Cl-containing intractable polymer films.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 91, Issue 2, February 2006, Pages 213-220
Journal: Polymer Degradation and Stability - Volume 91, Issue 2, February 2006, Pages 213-220
نویسندگان
Jadranka Blazevska-Gilev, Jaroslav KupÄÃk, Jan Å ubrt, ZdenÄk Bastl, VladimÃr VorlÃÄek, Anna GalÃková, Diana Spaseska, Josef Pola,