کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5205238 | 1502927 | 2017 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of the platinum catalyst content on the tracking and erosion resistance of addition-cure liquid silicone rubber
ترجمه فارسی عنوان
تأثیر محتوای کاتالیزور پلاتین بر ردیابی و مقاومت فرسایش لاستیک سیلیکون مایع افزودنی
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کلمات کلیدی
لاستیک سیلیکون مایع مخلوط، کاتالیزور پلاتین، ردیابی و فرسایش ردیابی فرسایش شیبدار و آزمایش فرسایش
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
An addition-cure liquid silicone rubber (ALSR) with ureido-containing MQ silicone resin (U-MTQ) was prepared by hydrosilylation with platinum catalyst (Pt). ALSR samples were characterized by thermogravimetric analysis (TGA) and thermogravimetry coupled with infrared spectroscopy (TG-FTIR), and the char layers of ALSR samples after inclined plate tracking and erosion test (IPT) were characterized by X-ray photoelectron spectroscopy (XPS). The effects of Pt content (5-100Â ppm) on the curing characteristics, mechanical properties and tracking and erosion resistance of ALSR were investigated. It was found that the cure rate increased with increase of Pt content. When the Pt content was 10Â ppm or 15Â ppm, the ALSR had excellent tracking and erosion resistance, all specimens could pass the 4.5Â kV level in IPT, and the erosion rate was only 0.13% and 0.15%, respectively. ALSR samples possessed optimum mechanical properties and thermal stability when the Pt content was 15Â ppm. TG-FTIR results showed that ALSR generated less carbonyl compounds (CH2O) and cyclic oligomers but more methane (CH4) when the Pt content was 15Â ppm. This demonstrated that there were lower levels of the oxidation of methyl groups and the main chain unzipping degradation of ALSR, and more homolysis of Si-CH3 during the degradation. The XPS results also showed that the macromolecular radicals would further cross-link to form a firm Si-C ceramic barrier to protect ALSR samples under Pt catalysis and high temperature, thus the tracking and erosion resistance of ALSR could be improved.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 63, October 2017, Pages 92-100
Journal: Polymer Testing - Volume 63, October 2017, Pages 92-100
نویسندگان
Yanping Li, Xingrong Zeng, Xuejun Lai, Hongqiang Li, Weizhen Fang,