کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5205950 | 1502942 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The use of relaxometry to evaluate the aging process in hybrid HIPS nanocomposites
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The use of relaxometry to evaluate the aging process in hybrid HIPS nanocomposites The use of relaxometry to evaluate the aging process in hybrid HIPS nanocomposites](/preview/png/5205950.png)
چکیده انگلیسی
Nuclear magnetic resonance allows measurement of proton spin-lattice relaxation times, which reflect the molecular mobility of the sample according to the changes in its chemical structure caused by different mechanisms that can be induced. Nanomaterials and their derivatives are good systems to investigate through NMR relaxometry due to their particular organization and intermolecular interaction. In this study, NMR relaxometry was employed to evaluate UV aging of HIPS nanomaterials formed by the solution method. The results obtained were quite interesting. Regardless of organoclay amount, the aging effect occurred slowly up to 200Â h of UV light exposure. However, at 300Â h of UV light exposure, competition between chain degradation and chain recombination occurred, and at 400Â h the aging effect increased the chain scission.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 48, December 2015, Pages 115-119
Journal: Polymer Testing - Volume 48, December 2015, Pages 115-119
نویسندگان
Paulo Sergio Rangel Cruz da Silva, Maria Inês Bruno Tavares,