کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5206017 | 1502945 | 2015 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synergistic effects of β-nucleating agent and ethylene-octene copolymer on toughening isotactic polypropylene
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The synergistic effects of β-nucleating agent and ethylene-octene copolymer on toughening isotactic polypropylene The synergistic effects of β-nucleating agent and ethylene-octene copolymer on toughening isotactic polypropylene](/preview/png/5206017.png)
چکیده انگلیسی
The mechanical properties of isotactic polypropylene (iPP) and ethylene-octene copolymer (POE) blends with or without β-nucleating agent (β-NA) were systematically studied. Results demonstrated that, after β-NA and POE were separately added, the impact strength of injection molded iPP samples increased. β-NA and POE were also found to have a synergistic toughening effect on iPP matrix, and the effect was significant. When the contents were 0.05 wt% β-NA and 10 wt% POE, the impact strength reached the maximum, i.e., almost 15 times that of neat iPP. SEM further revealed that POE in skin and core layers existed as long and narrow strips along the flow direction and throughout crystals. The tensile strength did not deteriorate because of the special phase morphology and tight interfacial interaction between POE phase and matrix. WAXD and DSC revealed that POE addition had negligible influence on crystal form, and a considerable number of β crystals was generated by adding β-NA. SEM results also confirmed a critical β-NA content. When β-NA content was lower than the critical value, perfect β sphaerocrystals were generated. When β-NA was higher, “bundle-like” crystal structures formed. Perfect β sphaerocrystals were more efficient for dissipating energy because of the looser stacking pattern, thus showing better toughness.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 45, August 2015, Pages 1-11
Journal: Polymer Testing - Volume 45, August 2015, Pages 1-11
نویسندگان
Feifei Wang, Hainan Du, Hong Liu, Yu Zhang, Xiongwei Zhang, Jie Zhang,