کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5206770 | 1382320 | 2012 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The influences of polyethylene glycol molecular weight on thermal stability, nonisothermal crystallization behavior, and morphology of poly(trimethylene terephthalate)/poly(ethylene oxide terephthalate) copolymers
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of poly(trimethylene terephthalate)/poly(ethylene oxide terephthalate) copolymers with approximately 25Â wt% PEG content were synthesized and investigated. The results showed that the thermal stability of copolymers increased with increasing Mn, PEG from 1000 to 4000Â g/mol. However, the thermal stability of the copolymer with Mn, PEGÂ =Â 300Â g/mol was better than the copolymer with Mn, PEGÂ =Â 600Â g/mol. The nonisothermal crystallization kinetics of the copolymers was analyzed using Ozawa and Mo models, and only the Mo method was satisfactory in describing this system. Polarized optical microscopy revealed that all copolymers could form ring banded spherulites and the temperature window for their formation was basically identical for all copolymers. In addition, the spherulitic growth rate curves of copolymers exhibited a bell shape, and both the maximum growth rate and the crystallization temperature corresponding to the maximum growth rate increased with the increase in Mn, PEG.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 31, Issue 5, August 2012, Pages 685-696
Journal: Polymer Testing - Volume 31, Issue 5, August 2012, Pages 685-696
نویسندگان
Zhenming Chen, Yan Liu, Chenguang Yao, Guisheng Yang,