کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5206789 | 1502958 | 2011 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In-line rheo-polarimetry: A method to measure in real time the flow birefringence during polymer extrusion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work presents a new optical detection system, an in-line rheo-polarimeter, to measure in real time polymer flow birefringence during extrusion. The total transmitted cross polarized light intensity is measured, converted into optical path difference, which is corrected for the transparent glass windows stress birefringence and then converted into the polymer flow birefringence in real time. To validate the in-line measurements, a bench assessment was done using cast sheets of polycarbonate with known optical path difference as standards. The flow birefringence of polystyrene was measured in-line during the extrusion process, attaining values up to â4Â ÃÂ 10â4, close to those found in the literature. The flow birefringence of various polystyrene samples was measured in-line during the extrusion showing the effect of increasing molecular weight on the polymer chain orientation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 30, Issue 8, December 2011, Pages 848-855
Journal: Polymer Testing - Volume 30, Issue 8, December 2011, Pages 848-855
نویسندگان
Kinglston Soares, Adillys Marcelo da Cunha Santos, Sebastião V. Canevarolo,