Material BehaviourFracture studies of polypropylene/nanoclay composite. Part II: Failure mechanism under fracture loads

In this second part of a two-part paper, the failure mechanism of polypropylene (PP)/nanoclay composite under fracture loads is presented. The PP/nanoclay composite was prepared via melt compounding in a twin-screw extruder. Maleic anhydride grafted polypropylene (MA-g-PP) was used as a compatibilizer to improve the dispersability of the clay. The PP/clay nanocomposite was characterized by XRD and SEM. XRD results show possibilities of exfoliation, and SEM studies rule out large-scale particle agglomeration. Fractographic observations of PP/clay nanocomposite at lower loading rates reveal that excessive fibrillation and impregnated fibrils arrest crack propagation, and the fracture occurs by void initiation at larger clay particles. As the loading rate increases, crazes combined with voids to accelerate crack propagation. At higher loading rates, cleavage type brittle fracture is observed.