کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5207690 1382363 2008 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Test MethodIntercomparison of slip flow velocity measurements of filled polymers by capillary extrusion rheometry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Test MethodIntercomparison of slip flow velocity measurements of filled polymers by capillary extrusion rheometry
چکیده انگلیسی

Slip flow can complicate both the measurement of the shear flow behaviour of polymers and the modelling of moulding processes. However, the understanding of the reliability of methods for measuring slip flow behaviour is limited. The results of an intercomparison on the measurement of slip flow behaviour by capillary extrusion rheometry of two polymer melts-a filled high-density polyethylene and a filled ethylene-vinyl acetate copolymer-are reported. Slip velocities were calculated, following the Mooney method, from the dependence of the shear stress-shear rate behaviour on the extrusion die diameter. Both compounds exhibited wall slip: in one case the slip velocity accounted for ≈80% of the total flow rate. Slip velocity results were typically within ≈±20% of the average values for the materials, although scatter up to ≈±40% was obtained for one material at high shear stresses. An analysis of slip velocity measurements indicated that uncertainties of 40-50% are typical (95% confidence level) although significantly higher uncertainties could result if testing conditions (primarily die diameters) are not optimised.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 27, Issue 3, May 2008, Pages 308-320
نویسندگان
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