کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5208496 | 1382580 | 2013 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of complex polymeric architectures using multilithiated carbanionic initiators-Comparison with other approaches
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This article reviews the various methods developed to generate di- and multicarbanionic lithiated initiators, the difficulties associated with their synthesis but also their potential in macromolecular engineering. It is shown that a wealth of complex macromolecular architectures based on monomers amenable to carbanionic polymerization can now be synthesized by divergent approach from these di- and multicarbanionic lithiated initiators. A comparison is made with other types of multifunctional initiators that have been developed from other living/controlled polymerizations, generating similar complex polymeric architectures from other monomers. A comparison is also made with the structures generated by the convergent carbanionic approach.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Polymer Science - Volume 38, Issue 1, January 2013, Pages 30-62
Journal: Progress in Polymer Science - Volume 38, Issue 1, January 2013, Pages 30-62
نویسندگان
Rachid Matmour, Yves Gnanou,