High-performance aromatic polyamides

Wholly aromatic polyamides (aramids) are considered to be high-performance organic materials due to their outstanding thermal and mechanical resistance. Their properties arise from their aromatic structure and amide linkages, which result in stiff rod-like macromolecular chains that interact with each other via strong and highly directional hydrogen bonds. These bonds create effective crystalline microdomains, resulting in a high-level intermolecular packing and cohesive energy. The better known commercial aramids, poly(p-phenylene terephthalamide) and poly(m-phenylene isophthalamide), are used in advanced technologies and have been transformed into high-strength and flame resistant fibers and coatings, with applications in the aerospace and armament industry, bullet-proof body armor, protective clothing, sport fabrics, electrical insulation, asbestos substitutes, and industrial filters, among others. Owing to their chemical structure, they exhibit extremely high transition temperatures that lie above their decomposition temperatures, are sparingly soluble in common organic solvents and, accordingly, can only be transformed upon solution. Research efforts are therefore underway to take advantage of their properties, enhance their processability and solubility, and incorporate new chemical functionalities in the polyamide backbone or lateral structure, so that their applicability is expanded and remains on the forefront of scientific research.