کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209765 | 1503072 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chemical surface functionalization of bulk poly (p-phenylene sulfide) yields a stable sulfonic acid catalyst
ترجمه فارسی عنوان
کاربرد عملیات شیمیایی سطحی پلی (سولفید پتاسیم) یک کاتالیزور اسید سولفونیک پایدار است
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Catalytic materials are important in industrial chemistry; these materials must be inexpensive and easy to process as well as resistant to chemicals, heat and structural loads. Poly (p-phenylene sulfide) (PPS) is a widely used and exceptionally resistant thermoplast. We demonstrate that the superficial regions of polymerized bulk PPS can be sulfonated using either SO3 or acetyl sulfate, yielding a solid core of unaltered PPS with a sulfonic acid-functionalized surface. The SO3 method was the most efficient and achieved 0.9Â mmol H+ per gram of polymer. We show that the sulfonated surfaces function as durable solid acid catalysts for the dehydration of ethanol to diethyl ether. We also develop a simple method for the formation of porous PPS structures based on compression molding and porogen leaching. Based on these results, we suggest that surface functionalization of bulk PPS can be used to develop a novel class of moldable, easily produced and durable heterogeneous catalysts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 88, March 2015, Pages 47-54
Journal: Reactive and Functional Polymers - Volume 88, March 2015, Pages 47-54
نویسندگان
Niklas Zwettler, Jakob S. Engbæk, Rasmus Lundsgaard, Irena Paranowska, Tina E. Nielsen, Stuart Clyens, Jens Christiansen, Morten Ã. Andersen,