کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209787 | 1503075 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Aligned unidirectional PLA/bacterial cellulose nanocomposite fibre reinforced PDLLA composites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In an effort to enhance the properties of polylactide (PLA), we have developed melt-spinning techniques to produce both PLA/nanocellulose composite fibres, and a method akin to layered filament winding followed by compression moulding to produce self-reinforced PLA/nanocellulose composites. Poly(L-lactide) (PLLA) fibres were filled with 2Â wt.% neat and modified bacterial cellulose (BC) in an effort to improve the tensile properties over neat PLA fibres. BC increased the viscosity of the polymer melt and reduced the draw-ratio of the fibres, resulting in increased fibre diameters. Nonetheless, strain induced chain orientation due to melt spinning led to PLLA fibres with enhanced tensile modulus (6Â GPa) and strength (127Â MPa), over monolithic PLLA, previously measured at 1.3Â GPa and 61Â MPa, respectively. The presence of BC also enhanced the nucleation and growth of crystals in PLA. We further produced PLA fibres with 7Â wt.% cellulose nanocrystals (CNCs), which is higher than the percolation threshold (equivalent to 6Â vol.%). These fibres were spun in multiple, alternating controlled layers onto spools, and subsequently compression moulded to produce unidirectional self-reinforced PLA composites consisting of 60Â vol.% PLLA fibres reinforced with 7Â wt.% CNC in a matrix of amorphous PDLLA, which itself contained 7Â wt.% of CNC. We observed improvements in viscoelastic properties of up to 175% in terms of storage moduli in bending. Furthermore, strains to failure for PLLA fibre reinforced PDLLA were recorded at 17%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 85, December 2014, Pages 185-192
Journal: Reactive and Functional Polymers - Volume 85, December 2014, Pages 185-192
نویسندگان
Jonny J. Blaker, Koon-Yang Lee, Matthew Walters, Marc Drouet, Alexander Bismarck,