کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209837 | 1503077 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of a main-chain donor-acceptor type low-bandgap polymer by post-functionalization of a poly(arylene ethynylene)
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
I report a facile synthetic route for synthesizing a main-chain donor-acceptor type polymer containing strong electron donating dialkylamino groups and strong electron accepting 1,1,4,4-tetracyanobuta-1,3-diene (TCBD) units. To accomplish this, an electron donating monomer 4,6-diethynyl-N,N,N,N-tetrahexylbenzene-1,3-diamine was successfully synthesized by converting two carbaldehyde groups in the corresponding monomer into acetylene groups using lithium trimethylsilyldiazomethane via Colvin rearrangement. This electron donating monomer was then polymerized with a carbonyl-activated diiodide monomer to afford an electron-donating Ï-conjugated precursor polymer with a reasonably high molecular weight, which was further reacted with TCNE via cycloaddition/retroelectrocyclization reaction under mild conditions to afford the target polymer with a low bandgap energy (Egopt=1.40eV and EgCV=1.10eV) arising from strong intramolecular charge-transfer interactions between electron donors and acceptors in the polymer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 83, October 2014, Pages 42-48
Journal: Reactive and Functional Polymers - Volume 83, October 2014, Pages 42-48
نویسندگان
Wenyi Huang,