کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5209990 | 1382868 | 2013 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of itaconimide/nadimide-functionalized benzoxazine monomers: Structural and thermal characterization
ترجمه فارسی عنوان
سنتز مونومرهای بنزوکسازین ایتاکونیمید / نادیمید-کاراکتر: مشخصات ساختاری و حرارتی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
A novel series of itaconimide/nadimide-functionalized benzoxazine monomers (I-Bz/N-Bz) from imide-terminated amines, paraformaldehyde and phenol/m-cresol/cardanol/4-(hydroxyphenyl) benzoxazole were synthesized and characterized by FT-IR, 1H and 13C NMR and HRMS analyses. The I-Bzs exhibited lower curing temperatures compared to the N-Bzs, which may be attributable to the presence of the 1,1-disubstituted double bond in itaconimide. The poly(I-Bz)s exhibited higher glass-transition temperatures (210-216 °C) compared to the poly(N-Bz)s (151-178 °C). The itaconimide- and nadimide-functionalized benzoxazines showed comparable thermal stability, but differences in their phenolic structures affected their thermal behavior (char yield and Tmax). The poly(I-Bz)s (19-47%) showed higher char yields compared to the poly(N-Bz)s (18-41%), depending on the backbone structure. The highest lap-shear strength at 200 °C was observed in I-Bz/N-Bz derived from m-cresol.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 73, Issue 11, November 2013, Pages 1544-1552
Journal: Reactive and Functional Polymers - Volume 73, Issue 11, November 2013, Pages 1544-1552
نویسندگان
Sini Nalakathu Kolanadiyil, Jayashree Bijwe, Indra K. Varma,