کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5210063 1503086 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Assembled diglycolamide for f-element ions sequestration at high acidity
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Assembled diglycolamide for f-element ions sequestration at high acidity
چکیده انگلیسی

Diglycolamides (DGA) form reverse-micellar type of supramolecular aggregates upon equilibration with a nitric acid solution that enhances DGA affinity extraordinary towards f-elements. To mimic DGA aggregates, DGA molecules have been preorganized on chemical platforms to form assemblies having a good affinity towards f-elements. However, the synthetic procedures used are quite laborious that limits their large scale applications. To address this problem, a new DGA-bearing monomer N,N-dioctyl,N′-propyl-2-methylacrylamide diglycolamide has been synthesized. This DGA-methacrylate monomer can be polymerized easily, and shows an interesting affinity towards f-element ions both in monomeric and polymeric forms at high nitric acid concentrations. This makes it very promising for the development of fixed-site membranes, resins, and magnetic assemblies for a variety of applications. DGA-methacrylate monomer has been found to assemble on magnetic nanoparticles Fe3O4. DGA-methacrylate coated Fe3O4 particles capture representative trivalent actinide 241Am with a very high efficiency. However, it has been observed that HNO3 induced preorganization of DGA-methacrylate plays an important role in sorption of f-element ions in the polymeric form and self-assembled molecules on the magnetic nanoparticles.

199

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 74, January 2014, Pages 52-57
نویسندگان
, , , , , , , ,