کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210382 | 1382891 | 2011 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Physico-chemical characterization of flavonol molecularly imprinted polymers
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Along the last decade considerable interest has been focused in deciphering the binding recognition process and the heterogeneity nature of binding sites in molecularly imprinted polymers (MIPs). Density Functional Theory (DFT) was employed at B3LYP/6-31+G** level of theory, to investigate the intermolecular interactions between the template flavonol and the functional monomer (methacrylic acid). The solvent effect energy stabilization of the monomer and template in different solvents was investigated by using the polarizable continuum method (PCM). The MIP against flavonol prepared using methacrylic acid as functional monomer was then characterized in terms of specific bindings by using Scatchard plot analysis. The rebinding properties were analyzed by equilibrium/rebinding batch experiments using the Langmuir, Bi-Langmuir, Freundlich, Langmuir-Freundlich, Jovanovich, Bi-Jovanovich and Jovanovich-Freundlich isotherms. The imprinted polymer was also characterized by continuous flow experiments, SEM and BET surface area measurements. Parallel studies were carried out with the non-imprinted polymer as control material.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 71, Issue 4, April 2011, Pages 402-408
Journal: Reactive and Functional Polymers - Volume 71, Issue 4, April 2011, Pages 402-408
نویسندگان
Luis E. Gómez-Pineda, Georgina E. Pina-Luis, Ángeles Cuán, Josefa A. GarcÃa-Calzón, Marta E. DÃaz-GarcÃa,