کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210829 | 1382919 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of poly(N-vinylcarbazole) having a C60 end-group by grafting poly(N-vinylcarbazolyl)lithium onto C60
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The grafting reaction of poly(N-vinylcarbazolyl)lithium (PNVCLi) with tert-butyllithium onto fullerene-C60 (C60) was examined to explore the possibility of preparing new materials for effective photovoltaic cells. When the molar ratio of C60/Li was over four, the grafting reaction products obtained were completely soluble in tetrahydrofuran. The number-average molecular weight of the grafting reaction products obtained was greater than that of the respective parent PNVCs, indicating the formation of PNVC with a C60 end-group. Gel permeation chromatography and 13C NMR analyses showed that the product of the grafting reaction was C60 bonded to PNVC and t-butyl groups. UV/vis and PL spectra suggested that this PNVC may be useful for preparing effective photovoltaic cells.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 68, Issue 8, August 2008, Pages 1266-1271
Journal: Reactive and Functional Polymers - Volume 68, Issue 8, August 2008, Pages 1266-1271
نویسندگان
Itaru Natori, Shizue Natori, Hiroyuki Sekikawa, Hisaya Sato,