کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5211046 1382934 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nanostructured biomimetic catalysts for asymmetric hydrogenation of enamides using molecular imprinting technology
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Nanostructured biomimetic catalysts for asymmetric hydrogenation of enamides using molecular imprinting technology
چکیده انگلیسی

A new class of heterogeneous catalysts for asymmetric hydrogenation of enamides was synthesized using molecular imprinting technology. These new catalysts are molecularly imprinted polymers (MIPs) made from rhodium (I) and copper (II) complexes with the bis(oxazoline) chiral ligands. One of the Rh-MIPs showed 87% ee toward L-enantiomeric product while the Cu-MIP showed 82% ee toward D-enantiomeric product. Both MIPs are easy to separate and reusable.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 69, Issue 9, September 2009, Pages 650-654
نویسندگان
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