کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5211315 | 1382944 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Novel polymerization of diethyl fumarate and maleate in aqueous media via cyclodextrin-complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Radical polymerization of cyclodextrin (CD) complexed diethyl fumarate (1) and diethyl maleate (2) was investigated using redox initiator in aqueous media at room temperature. Control experiments were carried out showing that 2 does not homopolymerize using radical initiator in bulk at 60 °C. Complex 2 undergoes homopolymerization with a cis/trans-isomerization in the presence of both CD and redox initiator. The obtained polymers have a similar structure and molecular weight as polymer obtained from the corresponding 1-CD complex. Additionally, the X-ray structure of a α-cyclodextrin complex of monomer 1 is represented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 66, Issue 1, January 2006, Pages 149-156
Journal: Reactive and Functional Polymers - Volume 66, Issue 1, January 2006, Pages 149-156
نویسندگان
SooWhan Choi, Walter Frank, Helmut Ritter,