کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5211587 1382958 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of novel macromonomers with polyether possessing fluorine and their polymerization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of novel macromonomers with polyether possessing fluorine and their polymerization
چکیده انگلیسی
Novel styrene-type and methacrylate (MA)-type macromonomers with polyether(poly(oxytetramethylene)) possessing a fluorobutyl terminal group were synthesized by the reaction between 4-aminostyrene or 2-hydroxyethyl methacrylate and polyether with a fluoroformyl group at one chain end (prepolymer), which was prepared by the ring-opening polymerization of THF with hexafluoropropylene oxide (HFPO) as an initiator. Macromonomers were easily prepared by mixing a solution containing the prepolymer with 4-aminostyrene or 2-hydroxyethyl methacrylate for several minutes at room temperature. The obtained macromonomers can polymerize with either radical or anionic initiator to afford polystyrene or poly(MA) with polyether grafted segment in each monomer unit.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 67, Issue 11, November 2007, Pages 1225-1232
نویسندگان
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