کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5212190 | 1383107 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Potential for minimal self-replicating systems in a dynamic combinatorial library of equilibrating imines
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Potential for minimal self-replicating systems in a dynamic combinatorial library of equilibrating imines Potential for minimal self-replicating systems in a dynamic combinatorial library of equilibrating imines](/preview/png/5212190.png)
چکیده انگلیسی
The presence of a self-replicator in a dynamic combinatorial library (DCL) offers function above and beyond libraries under thermodynamic control, moving towards out-of-equilibrium systems which mimic biological networks. In this work, we examine a previously reported DCL based on reversible imine formation to give amphiphilic structures. The amphiphilic imines were readily produced in organic solvents, and were found to aggregate to micelles in water as judged by diffusion-ordered NMR spectroscopy, dynamic light scattering and interferometric scattering microscopy. Unfortunately, the autocatalytic formation of products was not observed in water, and preformed imines slowly hydrolysed to aldehyde and amine components at neutral pD.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 73, Issue 33, 17 August 2017, Pages 5005-5010
Journal: Tetrahedron - Volume 73, Issue 33, 17 August 2017, Pages 5005-5010
نویسندگان
Sarah M. Morrow, Andrew J. Bissette, Stephen P. Fletcher,