کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5212330 | 1383112 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
One-pot synthesis of [6-5-6] tricyclic products via a double Diels-Alder/Nazarov tandem reaction of unsymmetrically substituted cross-conjugated diynones
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: One-pot synthesis of [6-5-6] tricyclic products via a double Diels-Alder/Nazarov tandem reaction of unsymmetrically substituted cross-conjugated diynones One-pot synthesis of [6-5-6] tricyclic products via a double Diels-Alder/Nazarov tandem reaction of unsymmetrically substituted cross-conjugated diynones](/preview/png/5212330.png)
چکیده انگلیسی
A highly concise one-pot method towards biologically pertinent compounds having a [6-5-6] tricyclic framework has been established. The multicomponent reaction utilizes a tandem, double Diels-Alder cycloaddition followed by a Nazarov reaction to furnish the [6-5-6] backbone. This method produces three fused rings evolving from the construction of five new carbon-carbon bonds, a quaternary carbon, and stereogenic centers in a one-pot reaction. The products are produced with excellent regio- and diastereocontrol.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 73, Issue 29, 20 July 2017, Pages 4084-4092
Journal: Tetrahedron - Volume 73, Issue 29, 20 July 2017, Pages 4084-4092
نویسندگان
Rachael A. Carmichael, Wesley A. Chalifoux,