کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5212437 | 1383116 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cyclopentadienyl-ruthenium(II) complexes as efficient catalysts for the reduction of carbonyl compounds
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
- CpRu(PPh3)2Cl is highly efficient catalyst for the reduction of carbonyl compounds.
- The reductions can be performed under solvent free conditions.
- The catalyst CpRu(PPh3)2Cl can be use in 12 catalytic cycles with excellent activity.
This work reports the reduction of a large variety of aldehydes and ketones with the system PhSiH3/[CpRu(PPh3)2Cl] in good to excellent yields and high chemoselectivity. The catalyst [CpRu(PPh3)2Cl] can be used in at least 12 catalytic cycles with excellent catalytic activity and several substrates were reduced under solvent free conditions.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 73, Issue 11, 16 March 2017, Pages 1511-1516
Journal: Tetrahedron - Volume 73, Issue 11, 16 March 2017, Pages 1511-1516
نویسندگان
Ivânia R. Cabrita, Pedro R. Florindo, Ana C. Fernandes,