کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5212884 1383136 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The chemical reactivities of DOPA and dopamine derivatives and their regioselectivities upon oxidative nucleophilic trapping
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
The chemical reactivities of DOPA and dopamine derivatives and their regioselectivities upon oxidative nucleophilic trapping
چکیده انگلیسی

The chemical reactivities of four catecholamines, N-acetyl dopamine (NADA) and its dehydro derivative (NAΔDA), N-acetyl 3,4-dihydroxy-phenylalanine methyl ester (NADOPAME) and its dehydro derivative (NAΔDOPAME), under oxidative nucleophilic trapping and polymerisation conditions were compared and contrasted. Despite their structural similarities, varying reactivities and regioselectivities for oxidative nucleophilic trapping with ethanethiol were observed. This has possible implications on the use of these natural building blocks and their derivatives in the design and synthesis of biomimetic materials.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 72, Issue 41, 13 October 2016, Pages 6543-6550
نویسندگان
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