کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5212907 | 1383137 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Experimental and theoretical study of stereochemistry for new pseurotin A3 with an unusual hetero-spirocyclic system
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Experimental and theoretical study of stereochemistry for new pseurotin A3 with an unusual hetero-spirocyclic system Experimental and theoretical study of stereochemistry for new pseurotin A3 with an unusual hetero-spirocyclic system](/preview/png/5212907.png)
چکیده انگلیسی
A new pseurotin A3 (3), which was obtained from the fungus Aspergillus terreus was converted into its acetyl derivative (4). Optical rotation (OR), 13C NMR, electronic circular dichroism (ECD) and vibrational circular dichroism (VCD) were measured for (+)-4 and computed for four possible isomers using quantum theory. Absolute configuration of (+)-4 was finally assigned as (5S,8S,9R,10S,11R,12Z) by comparing the predicted OR, ECD and VCD spectra to the experimental data. Therefore, the new compound 3 should have the (5S,8S,9R,10S,11R,12Z) too.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 72, Issue 45, 10 November 2016, Pages 7194-7199
Journal: Tetrahedron - Volume 72, Issue 45, 10 November 2016, Pages 7194-7199
نویسندگان
Lan-Lan Xu, Fei Cao, Qin Yang, Wan Li, Sha-Sha Tian, Hua-Jie Zhu, Yan-Yan Zhao, Xun Yang,