کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5213068 | 1383144 | 2016 | 5 صفحه PDF | دانلود رایگان |
A novel, silicon-linked, symmetric, V-shaped, coumarin derivative (1) with an electron-deficient 1,3,4-oxadiazoles unit and a phenyl moiety was synthesized and characterized. An efficient multifunctional organic light-emitting diode material was obtained through the use of optical, electrochemical, thermal, and theoretical investigations. We show that the Si atom induces a V-shaped structure that weakens π–π stacking and thus limits aggregation-induced quenching. As expected, a gradual transition from a locally excited state to an intramolecular charge-transfer state is observed with increasing solvent polarity. This new type of compound exhibits tunable light emission in solution making it a versatile emitter.
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Journal: Tetrahedron - Volume 72, Issue 47, 24 November 2016, Pages 7438–7442