کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5213438 | 1383156 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of the hydroxyl directing effect on the Paternò-Büchi reaction on 5-(2-triisopropylsilyloxazolyl)methanol derivatives
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The photochemical coupling of 5-oxazoylmethanol derivatives with benzophenone and benzaldehyde showed that the hydroxyl directing effect in the Paternò-Büchi reaction described in the case of allylic alcohols and furylmethanol derivatives can also be present in the case of 5-oxazolylmethanol derivatives. In this case, the reaction with aromatic aldehydes showed an unusual endo stereoselectivity. The observed stereoselectivity can be predicted on the basis of the interaction between HSOMO and LSOMO in the biradical intermediate.
The photochemical coupling of 5-oxazoylmethanol derivatives with benzophenone and benzaldehyde showed a hydroxyl directing effect.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 72, Issue 33, 18 August 2016, Pages 5142-5148
Journal: Tetrahedron - Volume 72, Issue 33, 18 August 2016, Pages 5142-5148
نویسندگان
Maurizio D'Auria, Rocco Racioppi, Federico Rofrano, Sonia Stoia, Licia Viggiani,