کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5213616 | 1383164 | 2016 | 15 صفحه PDF | دانلود رایگان |
To examine the substituent effect on the di-π-methane (DPM) rearrangement of barrelene-like skeleton, benzopyrazinobarrelene (BPB) and benzoquinoxalinobarrelene (BQB) were utilized as the photoreaction experimental platforms. By the installation of the pyrazine, the DPM reaction was limited to aza-di-π-methane reaction only, in terms of chemoselectivity. The results of the induced regioselectivity of DPM rearrangement of BPB and BQB with a wide variety of different substituents connected to the olefin/bridgehead position were examined.
To examine the substituent effect on the di-π-methane (DPM) rearrangement of barrelene-like skeleton, benzopyrazinobarrelene (BPB) and benzoquinoxalinobarrelene (BQB) were utilized as the photoreaction experimental platforms. By the installation of the pyrazine, the DPM reaction was limited to aza-di-π-methane reaction only, in terms of chemoselectivity. The results of the induced regioselectivity of DPM rearrangement of BPB and BQB with a wide variety of different substituents connected to the olefin/bridgehead position were examined.Figure optionsDownload as PowerPoint slide
Journal: Tetrahedron - Volume 72, Issue 10, 10 March 2016, Pages 1301–1315