کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5214817 | 1383208 | 2015 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Regioselective functionalization of sumanene
ترجمه فارسی عنوان
کاربردی مجدد سومانن
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Doubly functionalized dioxosumanene was designed and synthesized to extend Ï conjugation bi-directionally. Friedel-Crafts double cycloalkylation to sumanene proceeded selectively to give the cycloalkylated compound. This compound was suggested to be the flattened structure as compared to sumanene, which induced the facile bowl-to-bowl inversion. Oxidation of the benzylic position was performed, and then a carbonyl group at the reverse side of the cycloalkylated arene was selectively protected with acetal to afford the doubly functionalized dioxosumanene.
147
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 71, Issue 35, 2 September 2015, Pages 5906-5909
Journal: Tetrahedron - Volume 71, Issue 35, 2 September 2015, Pages 5906-5909
نویسندگان
Toru Amaya, Takanori Ito, Shun Katoh, Toshikazu Hirao,