کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5215395 | 1383228 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
8-Br-quinoline derivatives as sensitizers combining two-photon induced fluorescence and singlet oxygen generation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
The present study describes the synthesis of a series of original 8-Br-quinoline derivatives with an arylethynyl moiety at the C6 position, based on Friedländer and Sonogashira coupling key reactions. Investigation of their photophysical and two-photon absorption (2PA) properties reveals that these structures can lead to 2PA chromophores combining fluorescence and singlet oxygen generation properties. As a result, chromophores, which combine significant 2PA responses in the NIR region, good photosensitization ability (ΦÎ=0.4-0.6) and fluorescence properties (Φf=0.2-0.6) have been identified. These multifunctional derivatives hold promise as original dyes for combined two-photon imaging and photodynamic therapy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 71, Issue 7, 18 February 2015, Pages 1088-1094
Journal: Tetrahedron - Volume 71, Issue 7, 18 February 2015, Pages 1088-1094
نویسندگان
Sébastien Picard, Guillaume Clermont, Emilie Genin, Mireille Blanchard-Desce,