کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52168 | 46865 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A comparative study of SiO2- and ZrO2-supported zirconocene/MAO catalysts on ethylene/1-olefin copolymerization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In this present study, the use of silica and zirconia as a support for zirconocene/MAO catalyst for copolymerization of ethylene/1-olefin (1-hexene, 1-octene, and 1-decene) was investigated. First, MAO as the cocatalyst was impregnated onto the support. Then, copolymerization of ethylene/1-olefin was performed. It was found that the use of zirconia support showed promising activities compared to those of the silica. Increased activities can be attributed to higher amount of [Al]MAO present on the zirconia support coupled with strong interaction between the Osupport–Alcocatalyst linkage. In addition, the use of zirconia also resulted in higher degree of 1-olefin insertion and decreased Tm of copolymers produced.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1426–1431
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1426–1431
نویسندگان
Tipawan Pothirat, Bunjerd Jongsomjit, Piyasan Praserthdam,