کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5217469 1383297 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and photophysical studies of new pyrenylamino acids
ترجمه فارسی عنوان
سنتز و مطالعات فتوفیزیولوژیک اسید های جدید پیرنل آمینو
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی

Two new pyrenylamino acid derivatives were synthesized from β-bromodehydroalanine derivatives in good yields using addition and elimination reactions.The photophysical properties of the two new pyrenylamino acids were studied in several solvents. Steady-state and time-resolved fluorescence measurements revealed that the bipyrenylamino acid undergoes excimer formation, this process being solvent dependent. Rate constants for excimer formation and dissociation were calculated. The monopyrenylamino acid exhibits a photophysical behavior similar to that of pyrene, including the sensitivity to solvent polarity.The results point to a potential use of these new pyrenyl derivatives as fluorescent probes for peptides and proteins.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 69, Issue 48, 2 December 2013, Pages 10254-10261
نویسندگان
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