کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5218466 1383328 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Efficient, durable and reusable olefin metathesis catalysts with high affinity to silica gel
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Efficient, durable and reusable olefin metathesis catalysts with high affinity to silica gel
چکیده انگلیسی

The new Scorpio type olefin metathesis catalysts with very high affinity to silica gel are reported. After completion of the reaction, those complexes can be efficiently separated from reaction product by direct filtration of reaction mixture through a short pad of silica gel. Products obtained by this methodology are contaminated with low amounts of residual ruthenium. Especially, catalyst (H2IPr)(Cl)2RuC(H)(C6H4OR) (5b, R=CH(Me)(C(O)N(Me)OMe) exhibited very high activity and could be easily recovered and reused. Additionally, this catalyst was found to be effective already at 0.1-0.5 mol % and showed good compatibility with environmentally benign solvents.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 69, Issue 35, 2 September 2013, Pages 7408-7415
نویسندگان
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