کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5218615 | 1383332 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic applications of recyclable silica immobilized NHC-ruthenium complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A monosilylated Hoveyda-Grubbs ruthenium alkylidene has been prepared and grafted through the NHC ligand to a mesostructured silica, in refluxing toluene or at room temperature, giving two new organic-inorganic hybrid silica materials M2 and M3, respectively. While M3 exhibited good performances in several metathesis reactions, M2 showed good selectivity in the hydrosilylation of terminal alkynes, where the β-(Z)-vinylsilane was obtained as major product. Recycling of the supported catalysts without significant decrease in activity and selectivity was proven for at least three cycles in both transformations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 69, Issue 1, 7 January 2013, Pages 341-348
Journal: Tetrahedron - Volume 69, Issue 1, 7 January 2013, Pages 341-348
نویسندگان
Amà lia Monge-Marcet, Roser Pleixats, Xavier Cattoën, Michel Wong Chi Man,