کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5219119 | 1383348 | 2012 | 7 صفحه PDF | دانلود رایگان |
A series of novel calix[4]arene-based Mannich (5 and 6) and Schiff base (9-11) receptors have been synthesized and characterized by various analytical techniques. Competitive two-phase extraction experiments of these novel calix[4]arene amine- and imine-containing derivatives revealed a strong affinity for dichromate anions (Cr2O72â/HCr2O7â). The protonated alkylinium form of 5, 6 and 9-11 proved to be effective extractants for transferring the dichromate anions from an aqueous into an organic phase. Moreover, the extraction of dichromate anions by 5 and 9 in the presence of competitive anions such as Fâ, Clâ, Brâ, NO3â, NO2â, PO43â and SO42â showed that 5 and 9 could be selective anion receptors for dichromate anions in the presence of those anions.
Journal: Tetrahedron - Volume 68, Issue 42, 21 October 2012, Pages 8739-8745