کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5220322 1383384 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reaction of Tröger’s base analogues with Vilsmeier reagents
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Reaction of Tröger’s base analogues with Vilsmeier reagents
چکیده انگلیسی

As part of a program aimed at introducing functionality onto the Tröger’s base framework post-synthesis, we investigated the formylation reaction of Tröger’s base analogues with Vilsmeier reagents. We found that rather than the anticipated reaction at the aryl rings, these compounds react with Vilsmeier reagents to afford compounds with a modified strap, whereby the apical methylene group is replaced by a methylene strap bearing an N,N-disubstituted amine.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 67, Issue 44, 4 November 2011, Pages 8509–8514