کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5220379 | 1383386 | 2012 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC6 showed the effect of the terminal groups of ACPC6 on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 68, Issue 23, 10 June 2012, Pages 4368-4373
Journal: Tetrahedron - Volume 68, Issue 23, 10 June 2012, Pages 4368-4373
نویسندگان
Sunbum Kwon, Kyungtae Kang, Aram Jeon, Ji Hun Park, Insung S. Choi, Hee-Seung Lee,