کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5220662 | 1383395 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Organocatalyzed arylalkylation of activated alkenes via decarboxylation of PhI(O2CR)2: efficient synthesis of oxindoles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel organocatalyzed arylalkylation of activated alkenes has been developed. This reaction was initiated from the decomposition of PhI(O2CR)2 to generate alkyl radical, followed by addition to alkenes. Then the formed radical was trapped by aromatic ring to generate the cyclized products. This method presents an efficient road to synthesis of a variety of oxindoles.
A novel organocatalyzed arylalkylation of activated alkenes has been developed. This reaction was initiated from the decomposition of PhI(O2CR)2 to generate alkyl radical, followed by addition to alkenes. Then the formed radical was trapped by aromatic ring to generate the cyclized products. This method presents an efficient road to synthesis of a variety of oxindoles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 68, Issue 26, 1 July 2012, Pages 5229-5233
Journal: Tetrahedron - Volume 68, Issue 26, 1 July 2012, Pages 5229-5233
نویسندگان
Tao Wu, Hao Zhang, Guosheng Liu,