کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5222007 1383439 2009 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Anodic oxidations and polarity: exploring the chemistry of olefinic radical cations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Anodic oxidations and polarity: exploring the chemistry of olefinic radical cations
چکیده انگلیسی

The cyclization chemistry of radical cations derived from electron-rich olefins has been examined and the relationship between the polarization of the radical cation and the chemoselectivity of the reaction probed. It was found that more polarized radical cations favor carbon-carbon bond formation while less polarized radical cations favor carbon-heteroatom bond formation. A new approach to the synthesis of quaternary carbons was uncovered and the compatibility of ene diol ethers with anodic olefin coupling reactions examined.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 52, 26 December 2009, Pages 10863-10875
نویسندگان
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