کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5222076 1383442 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Steric effects on controlling of photoinduced electron transfer action of anthracene modified benzo-15-crown-5 by complexation with Mg2+ and Ca2+
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Steric effects on controlling of photoinduced electron transfer action of anthracene modified benzo-15-crown-5 by complexation with Mg2+ and Ca2+
چکیده انگلیسی

Benzo-crown ether based chemosensors linked by an amide bond at the 1-, 2- or 9-positions of anthracene rings were synthesized. Their complexation behavior with alkaline earth metal ions in acetonitrile was investigated using fluorescence, UV, and 1H NMR spectroscopy. In the absence of a metal ion, all compounds showed only very slight fluorescence emissions (fluorescence 'off' state) because of intramolecular charge/electron transfer process. After the complex formation with Mg2+ and Ca2+, however, only the 2-position analogue gave a fluorescence 'on' response by inhibiting the photoinduced electron transfer. Because 2-positioned anthracene was free from steric hindrance of the crown ether ring, a strongly bent complex structure was formed with Mg2+ and Ca2+, which induced a breakdown of π-conjugation between the amide moiety and the benzene ring.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 67, Issue 26, 1 July 2011, Pages 4814-4819
نویسندگان
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