کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5222113 1383443 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Lewis acid-catalyzed oxidative rearrangement of tertiary allylic alcohols mediated by TEMPO
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Lewis acid-catalyzed oxidative rearrangement of tertiary allylic alcohols mediated by TEMPO
چکیده انگلیسی

Two methods for the oxidative rearrangement of tertiary allylic alcohols have been developed. Most of tertiary allylic alcohols studied were oxidized to their corresponding transposed carbonyl derivatives in excellent to fair yields by reaction with TEMPO in combination with PhIO and Bi(OTf)3 or copper (II) chloride in the presence or not of oxygen. Other primary oxidants of TEMPO such as PhI(OAc)2, mCPBA, and Oxone® were unsatisfactory giving the enone in modest to low yields.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 66, Issue 4, 23 January 2010, Pages 904-912
نویسندگان
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